Difference between revisions of "Published Organic Reactions chapters"

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Revision as of 17:24, 28 February 2012

Reformatsky Reaction (1)
Arndt-Eistert Reaction
Chloromethylation of Aromatic Compounds
Amination of Heterocyclic Bases by Alkali Amides
Bucherer Reaction
Elbs Reaction
Clemmensen Reduction
Perkin Reaction and Related Reactions
Acetoacetic Ester Condensation and Certain Related Reactions
Mannich Reaction
Fries Reaction
Jacobsen Reaction
Claisen Rearrangement
Preparation of Aliphatic Fluorine Compounds
Cannizzaro Reaction
Formation of Cyclic Ketones by Intramolecular Acylation
Reduction with Aluminum Alkoxides (The Meerwein-Ponndorf-Verley Reduction)
Preparation of Unsymmetrical Biaryls by the Diazo Reaction and the Nitrosoacetylamine Reaction
Replacement of the Aromatic Primary Amino Group by Hydrogen
Periodic Acid Oxidation
Resolution of Alcohols
Preparation of Aromatic Arsonic and Arsinic Acids by the Bart, Béchamp, and Rosenmund Reactions
Alkylation of Aromatic Compounds by the Friedel-Crafts Method
Willgerodt Reaction
Preparation of Ketenes and Ketene Dimers
Direct Sulfonation of Aromatic Hydrocarbons and Their Halogen Derivatives
Substitution and Addition Reactions of Thiocyanogen
Hofmann Reaction
Schmidt Reaction (1)
Curtius Reaction
Diels-Alder Reaction with Maleic Anhydride
Diels-Alder Reaction: Ethylenic and Acetylenic Dienophiles
Preparation of Amines by Reductive Alkylation
Synthesis of Benzoins
Synthesis of Benzoquinones by Oxidation
Rosenmund Reduction of Acid Chlorides to Aldehydes
Wolff-Kishner Reduction
Synthesis of Acetylenes
Diels-Alder Reaction: Quinones and Other Cyclenones
Preparation of Aromatic Fluorine Compounds from Diazonium Fluoborates: The Schiemann Reaction
Friedel and Crafts Reaction with Aliphatic Dibasic Acid Anhydrides
Gattermann-Koch Reaction
Leuckart Reaction
Selenium Dioxide Oxidation (1)
Hoesch Synthesis
Darzens Glycidic Ester Condensation
Stobbe Condensation
Preparation of 3,4-Dihydroisoquinolines and Related Compounds by the Bischler-Napieralski Reaction
Pictet-Spengler Synthesis of Tetrahydroisoquinolines and Related Compounds
Synthesis of Isoquinolines by the Pomeranz-Fritsch Reaction
Oppenauer Oxidation
Synthesis of Phosphonic and Phosphinic Acids
Halogen-Metal Interconversion Reaction with Organolithium Compounds
Preparation of Thiazoles
Preparation of Thiophenes and Tetrahydrothiophenes
Reductions by Lithium Aluminum Hydride
Pechmann Reaction
Skraup Synthesis of Quinolines
Carbon-Carbon Alkylations with Amines and Ammonium Salts
Von Braun Cyanogen Bromide Reaction
Hydrogenolysis of Benzyl Groups Attached to Oxygen, Nitrogen, or Sulfur
Nitrosation of Aliphatic Carbon Atoms
Epoxidation and Hydroxylation of Ethylenic Compounds with Organic Peracids
Catalytic Hydrogenation of Esters to Alcohols
Synthesis of Ketones from Acid Halides and Organometallic Compounds of Magnesium, Zinc, and Cadmium
Acylation of Ketones to Form beta-Diketones or beta-Keto Aldehydes
Sommelet Reaction
Synthesis of Aldehydes from Carboxylic Acids
Metalation Reaction with Organolithium Compounds
Beta Lactones
Reaction of Diazomethane and Its Derivatives with Aldehydes and Ketones
Cleavage of Non-enolizable Ketones with Sodium Amide
Gattermann Synthesis of Aldehydes
Baeyer-Villiger Oxidation of Aldehydes and Ketones
Alkylation of Esters and Nitriles
Reaction of Halogens with Silver Salts of Carboxylic Acids
Synthesis of beta-Lactams
Pschorr Synthesis and Related Diazonium Ring Closure Reactions
Coupling of Diazonium Salts with Aliphatic Carbon Atoms
Japp-Klingemann Reaction
Michael Reaction
Beckmann Rearrangement
Demjanov and Tiffeneau-Demjanov Ring Expansions
Arylation of Unsaturated Compounds by Diazonium Salts
Favorskii Rearrangement of Haloketones
Olefins from Amines: The Hofmann Elimination Reaction and Amine Oxide Pyrolysis
Cyclobutane Derivatives from Thermal Cycloaddition Reactions
Preparation of Olefins by the Pyrolysis of Xanthates. The Chugaev Reaction
Synthesis of Aliphatic and Alicyclic Nitro Compounds
Synthesis of Peptides with Mixed Anhydrides
Desulfurization with Raney Nickel
Hydration of Olefins, Dienes, and Acetylenes via Hydroboration
Halocyclopropanes from Halocarbenes
Free Radical Addition to Olefins to Form Carbon-Carbon Bonds
Formation of Carbon-Heteroatom Bonds by Free Radical Chain Additions to Carbon-Carbon Multiple Bonds
Chapman Rearrangement
A-Amidoalkylations at Carbon
Wittig Reaction
Dieckmann Condensation
Knoevenagel Condensation
Aldol Condensation
Synthesis of Substituted Ferrocenes and Other pi-Cyclopentadienyl-Transition Metal Compounds
Gamma-Alkylation and gamma-Arylation of Dianions of beta-Dicarbonyl Compounds
Ritter Reaction
Preparation of Ketones from the Reaction of Organolithium Reagents with Carboxylic Acids
Smiles and Related Rearrangements of Aromatic Systems
Reactions of Diazoacetic Esters with Alkenes, Alkynes, Heterocyclic, and Aromatic Compounds
Base-Promoted Rearrangements of Quaternary Ammonium Salts
Conjugate Addition Reactions of Organocopper Reagents
Formation of Carbon-Carbon Bonds via π-Allylnickel Compounds
Thiele-Winter Acetoxylation of Quinones
Oxidative Decarboxylation of Acids by Lead Tetraacetate
Cyclopropanes from Unsaturated Compounds, Methylene Iodide, and Zinc-Copper Couple
Sensitized Photooxygenation of Olefins
Synthesis of 5-Hydroxyindoles by the Nenitzescu Reaction
Zinin Reaction of Nitroarenes
Fluorination with Sulfur Tetrafluoride
Modern Methods to Prepare Monofluoroaliphatic Compounds
Claisen and Cope Rearrangements
Substitution Reactions Using Organocopper Reagents
Clemmensen Reduction of Ketones in Anhydrous Organic Solvents
Reformatsky Reaction (2)
Reduction and Related Reactions of alpha beta-Unsaturated Compounds with Metals in Liquid Ammonia
Acyloin Condensation
Alkenes from Tosylhydrazones
Homogeneous Hydrogenation Catalysts in Organic Solvents
Ester Cleavages via SN2-Type Dealkylation
Arylation of Unsaturated Compounds by Diazonium Salts (The Meerwein Arylation Reaction)
Selenium Dioxide Oxidation (2)
Ramberg-Bäcklund Rearrangement
Synthetic Applications of Phosphoryl-Stabilized Anions
Hydrocyanation of Conjugated Carbonyl Compounds
Heteroatom-Facilitated Lithiations
Intramolecular Reactions of Diazocarbonyl Compounds
Allylic and Benzylic Carbanions Substituted by Heteroatoms
Palladium-Catalyzed Vinylation of Organic Halides
Reimer-Tiemann Reaction
Friedländer Synthesis of Quinolines
Directed Aldol Reaction
Replacement of Alcoholic Hydroxy Groups by Halogens and Other Nucleophiles via Oxyphosphonium Intermediates
Reductive Dehalogenation of Polyhalo Ketones with Low-Valent Metals and Related Reducing Agents
Base-Promoted Isomerizations of Epoxides
Photocyclization of Stilbenes and Related Molecules
Olefin Synthesis via Deoxygenation of Vicinal Diols
Addition and Substitution Reactions of Nitrile-Stabilized Carbanions
Intramolecular Diels-Alder Reaction
Syntheses Using Alkyne-Derived Alkenyl- and Alkynylaluminum Compounds
Formation of Carbon-Carbon and Carbon-Heteroatom Bonds via Organoboranes and Organoborates
Vinylcyclopropane-Cyclopentene Rearrangement
Reductions by Metal Alkoxyaluminum Hydrides
Fluorination by Sulfur Tetrafluoride
Beckmann Reactions: Rearrangements, Elimination-Additions, Fragmentations, and Rearrangement-Cyclizations
Persulfate Oxidation of Phenols and Arylamines (The Elbs and the Boyland-Sims Oxidations)
Fluorination with Diethylaminosulfur Trifluoride and Related Aminofluorosulfuranes
3+2 Nitrone-Olefin Cycloaddition Reaction
Phosphorus Addition at sp2 Carbon
Reduction by Metal Alkoxyaluminum Hydrides. Part II. Carboxylic Acids and Derivatives, Nitrogen Compounds, and Sulfur Compounds
Chiral Synthons by Ester Hydrolysis Catalyzed by Pig Liver Esterase
Electrophilic Substitution of Allylsilanes and Vinylsilanes
Peterson Olefination Reaction
Tandem Vicinal Difunctionalization: beta-Addition to alpha beta-Unsaturated Carbonyl Substrates Followed by alpha-Functionalization
Nef Reaction
Lithioalkenes from Arenesulfonylhydrazones
Polonovski Reaction
Oxidation of Alcohols to Carbonyl Compounds via Alkoxysulfonium Ylides: The Moffatt, Swern, and Related Oxidations
Pauson-Khand Cycloaddition Reaction for Synthesis of Cyclopentenones
Reduction with Diimide
Pummerer Reaction of Sulfinyl Compounds
Catalyzed Nucleophilic Addition of Aldehydes to Electrophilic Double Bonds
Divinylcyclopropane-Cycloheptadiene Rearrangement
Organocopper Reagents: Substitution, Conjugate Addition, Carbo/Metallo-cupration, and Other Reactions
Birch Reduction of Aromatic Compounds
Mitsunobu Reaction
Carbonyl Methylenation and Alkylidenation Using Titanium-Based Reagents
Anion-Assisted Sigmatropic Rearrangements
Baeyer-Villiger Oxidation of Ketones and Aldehydes
Preparation of alpha beta-Unsaturated Carbonyl Compounds and Nitriles by Selenoxide Elimination
Enone Olefin 2+2 Photochemical Cycloadditions
Nazarov Cyclization
Ketene Cycloadditions
Tin(II) Enolates in the Aldol, Michael, and Related Reactions
2,3-Wittig Rearrangement
Reductions with Samarium(II) Iodide
Lateral Lithiation Reactions Promoted by Heteroatomic Substituents
Intramolecular Michael Reaction
Asymmetric Epoxidation of Allylic Alcohols: The Katsuki-Sharpless Epoxidation Reaction
Radical Cyclization Reactions
Vilsmeier Reaction of Fully Conjugated Carbocycles and Heterocycles
6+4 Cycloaddition Reactions
Carbon-Carbon Bond-Forming Reactions Promoted by Trivalent Manganese
Stille Reaction
Asymmetric Aldol Reactions Using Boron Enolates
Catalyzed a-Hydroxyalkylation and a-Aminoalkylation of Activated Olefins (The Morita–Baylis–Hillman Reaction)
4+3 Cycloaddition Reactions
Retro–Diels–Alder Reaction. Part I. C–C Dienophiles
Enantioselective Reduction of Ketones
Oxidation of Alcohols by Modified Oxochromium(VI)-Amine Complexes
Retro-Diels-Alder Reaction. Part II. Dienophiles with One or More Heteroatoms
Aromatic Substitution by the SRN1 Reaction
Oxidation of Carbonyl Compounds with Organohypervalent Iodine Reagents
Synthesis of Nucleosides
Hydroformylation Reaction
Vilsmeier Reaction. 2. Reactions with Compounds Other Than Fully Conjugated Carbocycles and Heterocycles
Intermolecular Metal-Catalyzed Carbenoid Cyclopropanations
Oxidation of Phenolic Compounds with Organohypervalent Iodine Reagents
Synthetic Uses of Tosylmethyl Isocyanide (TosMIC)
Simmons-Smith Cyclopropanation Reaction
Preparation and Applications of Functionalized Organozinc Compounds
Reductive Aminations of Carbonyl Compounds with Borohydride and Borane Reducing Agents
Epoxide Migration (Payne Rearrangement) and Related Reactions
Intramolecular Heck Reaction
3+2 Cycloaddition of Trimethylenemethane and its Synthetic Equivalents
Dioxirane Epoxidation of Alkenes
Alpha-Hydroxylation of Enolates and Silyl Enol Ethers
Ramberg-Bäcklund Reaction
Alpha-Hydroxy Ketone (alpha-Ketol) and Related Rearrangements
Transformation of Glycals into 2,3-Unsaturated Glycosyl Derivatives
Biginelli Dihydropyrimidine Synthesis
Microbial Arene Oxidations
Cu, Ni, and Pd Mediated Homocoupling Reactions in Biaryl Syntheses: The Ullmann Reaction
Additions of Allyl, Allenyl, and Propargylstannanes to Aldehydes and Imines
Glycosylation with Sulfoxides and Sulfinates as Donors or Promoters
Addition of Organochromium Reagents to Carbonyl Compounds
Passerini Reaction
Diels-Alder Reactions of Imino Dienophiles
Allylic Trihaloacetimidate Rearrangment
Asymmetric Dihydroxylation of Alkenes
Catalytic Enantioselective Aldol Addition Reactions
Benzylic Activation and Stereocontrol in Tricarbonyl(arene)chromium Complexes
Cotrimerizations of Acetylenic Comounds
Glycosylation on Polymer Supports
Dioxirane Oxidations of Compounds Other Than Alkenes
Electrophilic Fluorination with N-F Reagents
Catalytic Asymmetric Strecker Reaction
Synthesis of Phenols and Quinones via Fischer Carbenes
Ionic and Organometallic-Catalyzed Organosilane Reductions
Electrophilic Amination of Carbanions, Enolates, and Their Surrogates
Desulfonylation Reactions
Allylboration of Carbonyl Compounds
Catalytic Asymmetric Hydrogenation Of C=N Functions
Oxoammonium and Nitroxide-catalyzed Oxidations of Alcohols
Asymmetric Epoxidation Of Electron-Deficient Alkenes
Hydrocyanation of Alkenes and Alkynes
Intermolecular C-H Insertions of Carbenoids
Cross-Coupling with Organosilicon Compounds
The Aza-Cope/Mannich Reaction
Hydrogen-bonding-mediated Directed Osmium Dihydroxylation
Transition-metal-catalyzed a-Arylation of Enolates
Indoles via Palladium-catalyzed Cyclization
The Barton-McCombie Reaction
Kulinkovich Cyclopropanation of Carboxylic Acid Derivatives
The Schmidt Reaction (2)
The Neber Rearrangement
Twofold Extrusion Reactions
Cross-coupling Reactions of Organotrifluoroborate Salts
Asymmetric Transformations by Deprotonation Using Chiral Lithium Amides
Catalytic, Asymmetric, Intramolecular Carbon-Hydrogen Insertion
Cycloadditions of Carbonyl Ylides Derived from Diazocarbonyl Compounds
Krapcho Dealkoxycarbonylation Reaction of Esters with alpha-Electron-withdrawing Substituents
McMurry Coupling and Related Reactions
Catalytic Asymmetric Ketene 2 + 2 and 4 + 2 Cycloadditions
Iron-catalyzed Cross-coupling Reactions
The Boronic Acid Mannich Reaction
Molybdenum-catalyzed Asymmetric Allylic Alkylations
The Wacker Oxidation
Copper-Catalyzed Amination of Aryl and Alkenyl Electrophiles
Ring-Expanding Carbonylation of Epoxides
The Tishchenko Reaction
Oxidative Cleavage of Furans
Cycloaddition and Electrocyclization Reactions of Vinylketenes, Allenylketenes, and Alkynylketenes
Carbozincation Reactions of Carbon-Carbon Multiple Bonds
Hydroamination of Alkenes
Olefin Ring-closing Metathesis
The Catalytic, Enantioselective Michael Reaction
Nucleophilic Additions of Perfluoroalkyl Groups
Gold-catalyzed Cyclizations of Alkynes with Alkenes and Arenes
Cyclizations of Vinyl and Aryl Azides into Pyrroles, Indoles, Carbazoles, and Related Fused Pyrroles
Asymmetric Rhodium-Catalyzed 1,4-Addition of Organoboron Reagents
3+2 Dipolar Cycloadditions of Cyclic Nitrones with Alkenes
The Julia-Kocienski Olefination
Asymmetric Synthesis of β-Lactams by the Staudinger Reaction
Catalytic, Enantioselective Hydrogenation of Heteroaromatic Compounds
Transition Metal Catalyzed Hydroacylation
2+2+2 Cycloadditions of Alkynes with Heterocumulenes and Nitriles
Amide-forming Ligation Reactions
The Saegusa Oxidation and Related Procedures
The Asymmetric Vinylogous Mukaiyama Aldol Reaction