Difference between revisions of "Published Organic Reactions chapters"

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Revision as of 18:07, 6 June 2011

2+2+2 Cycloadditions of Alkynes with Heterocumulenes and Nitriles97
2,3-Wittig Rearrangement46
3+2 Cycloaddition of Trimethylenemethane and its Synthetic Equivalents61
3+2 Dipolar Cycloadditions of Cyclic Nitrones with Alkenes94
3+2 Nitrone-Olefin Cycloaddition Reaction36
4+3 Cycloaddition Reactions51
6+4 Cycloaddition Reactions49
A-Amidoalkylations at Carbon14
Acetoacetic Ester Condensation and Certain Related Reactions1
Acylation of Ketones to Form beta-Diketones or beta-Keto Aldehydes8
Acyloin Condensation23
Addition and Substitution Reactions of Nitrile-Stabilized Carbanions31
Addition of Organochromium Reagents to Carbonyl Compounds64
Additions of Allyl, Allenyl, and Propargylstannanes to Aldehydes and Imines64
Aldol Condensation16
Alkenes from Tosylhydrazones23
Alkylation of Aromatic Compounds by the Friedel-Crafts Method3
Alkylation of Esters and Nitriles9
Allylboration of Carbonyl Compounds73
Allylic Trihaloacetimidate Rearrangment66
Allylic and Benzylic Carbanions Substituted by Heteroatoms27
Alpha-Hydroxy Ketone (alpha-Ketol) and Related Rearrangements62
Alpha-Hydroxylation of Enolates and Silyl Enol Ethers62
Amide-forming Ligation Reactions97
Amination of Heterocyclic Bases by Alkali Amides1
Anion-Assisted Sigmatropic Rearrangements43
Arndt-Eistert Reaction1
Aromatic Substitution by the SRN1 Reaction54
Arylation of Unsaturated Compounds by Diazonium Salts11
Arylation of Unsaturated Compounds by Diazonium Salts (The Meerwein Arylation Reaction)24
Asymmetric Aldol Reactions Using Boron Enolates51
Asymmetric Dihydroxylation of Alkenes66
Asymmetric Epoxidation Of Electron-Deficient Alkenes74
Asymmetric Epoxidation of Allylic Alcohols: The Katsuki-Sharpless Epoxidation Reaction48
Asymmetric Rhodium-Catalyzed 1,4-Addition of Organoboron Reagents93
Asymmetric Synthesis of β-Lactams by the Staudinger Reaction95
Asymmetric Transformations by Deprotonation Using Chiral Lithium Amides79
Baeyer-Villiger Oxidation of Aldehydes and Ketones9
Baeyer-Villiger Oxidation of Ketones and Aldehydes43
Base-Promoted Isomerizations of Epoxides29
Base-Promoted Rearrangements of Quaternary Ammonium Salts18
Beckmann Reactions: Rearrangements, Elimination-Additions, Fragmentations, and Rearrangement-Cyclizations35
Beckmann Rearrangement11
Benzylic Activation and Stereocontrol in Tricarbonyl(arene)chromium Complexes67
Beta Lactones8
Biginelli Dihydropyrimidine Synthesis63
Birch Reduction of Aromatic Compounds42
Bucherer Reaction1
Cannizzaro Reaction2
Carbon-Carbon Alkylations with Amines and Ammonium Salts7
Carbon-Carbon Bond-Forming Reactions Promoted by Trivalent Manganese49
Carbonyl Methylenation and Alkylidenation Using Titanium-Based Reagents43
Carbozincation Reactions of Carbon-Carbon Multiple Bonds87
Catalytic Asymmetric Hydrogenation Of C=N Functions74
Catalytic Asymmetric Ketene 2 + 2 and 4 + 2 Cycloadditions82
Catalytic Asymmetric Strecker Reaction70
Catalytic Enantioselective Aldol Addition Reactions67
Catalytic Hydrogenation of Esters to Alcohols8
Catalytic, Asymmetric, Intramolecular Carbon-Hydrogen Insertion80
Catalytic, Enantioselective Hydrogenation of Heteroaromatic Compounds96
Catalyzed Nucleophilic Addition of Aldehydes to Electrophilic Double Bonds40
Catalyzed a-Hydroxyalkylation and a-Aminoalkylation of Activated Olefins (The Morita–Baylis–Hillman Reaction)51
Chapman Rearrangement14
Chiral Synthons by Ester Hydrolysis Catalyzed by Pig Liver Esterase37
Chloromethylation of Aromatic Compounds1
Claisen Rearrangement2
Claisen and Cope Rearrangements22
Cleavage of Non-enolizable Ketones with Sodium Amide9
Clemmensen Reduction1
Clemmensen Reduction of Ketones in Anhydrous Organic Solvents22
Conjugate Addition Reactions of Organocopper Reagents19
Copper-Catalyzed Amination of Aryl and Alkenyl Electrophiles85
Cotrimerizations of Acetylenic Comounds68
Coupling of Diazonium Salts with Aliphatic Carbon Atoms10
Cross-Coupling with Organosilicon Compounds75
Cross-coupling Reactions of Organotrifluoroborate Salts79
Cu, Ni, and Pd Mediated Homocoupling Reactions in Biaryl Syntheses: The Ullmann Reaction63
Curtius Reaction3
Cyclizations of Vinyl and Aryl Azides into Pyrroles, Indoles, Carbazoles, and Related Fused Pyrroles92
Cycloaddition and Electrocyclization Reactions of Vinylketenes, Allenylketenes, and Alkynylketenes87
Cycloadditions of Carbonyl Ylides Derived from Diazocarbonyl Compounds80
Cyclobutane Derivatives from Thermal Cycloaddition Reactions12
Cyclopropanes from Unsaturated Compounds, Methylene Iodide, and Zinc-Copper Couple20
Darzens Glycidic Ester Condensation5
Demjanov and Tiffeneau-Demjanov Ring Expansions11
Desulfonylation Reactions72
Desulfurization with Raney Nickel12
Dieckmann Condensation15
Diels-Alder Reaction with Maleic Anhydride4
Diels-Alder Reaction: Ethylenic and Acetylenic Dienophiles4
Diels-Alder Reaction: Quinones and Other Cyclenones5
Diels-Alder Reactions of Imino Dienophiles65
Dioxirane Epoxidation of Alkenes61
Dioxirane Oxidations of Compounds Other Than Alkenes69
Direct Sulfonation of Aromatic Hydrocarbons and Their Halogen Derivatives3
Directed Aldol Reaction28
Divinylcyclopropane-Cycloheptadiene Rearrangement41
Elbs Reaction1
Electrophilic Amination of Carbanions, Enolates, and Their Surrogates72
Electrophilic Fluorination with N-F Reagents69
Electrophilic Substitution of Allylsilanes and Vinylsilanes37
Enantioselective Reduction of Ketones52
Enone Olefin 2+2 Photochemical Cycloadditions44
Epoxidation and Hydroxylation of Ethylenic Compounds with Organic Peracids7
Epoxide Migration (Payne Rearrangement) and Related Reactions60
Ester Cleavages via SN2-Type Dealkylation24
Favorskii Rearrangement of Haloketones11
Fluorination by Sulfur Tetrafluoride34
Fluorination with Diethylaminosulfur Trifluoride and Related Aminofluorosulfuranes35
Fluorination with Sulfur Tetrafluoride21
Formation of Carbon-Carbon Bonds via π-Allylnickel Compounds19
Formation of Carbon-Carbon and Carbon-Heteroatom Bonds via Organoboranes and Organoborates33
Formation of Carbon-Heteroatom Bonds by Free Radical Chain Additions to Carbon-Carbon Multiple Bonds13
Formation of Cyclic Ketones by Intramolecular Acylation2
Free Radical Addition to Olefins to Form Carbon-Carbon Bonds13
Friedel and Crafts Reaction with Aliphatic Dibasic Acid Anhydrides5
Friedländer Synthesis of Quinolines28
Fries Reaction1
Gamma-Alkylation and gamma-Arylation of Dianions of beta-Dicarbonyl Compounds17
Gattermann Synthesis of Aldehydes9
Gattermann-Koch Reaction5
Glycosylation on Polymer Supports68
Glycosylation with Sulfoxides and Sulfinates as Donors or Promoters64
Gold-catalyzed Cyclizations of Alkynes with Alkenes and Arenes92
Halocyclopropanes from Halocarbenes13
Halogen-Metal Interconversion Reaction with Organolithium Compounds6
Heteroatom-Facilitated Lithiations26
Hoesch Synthesis5
Hofmann Reaction3
Homogeneous Hydrogenation Catalysts in Organic Solvents24
Hydration of Olefins, Dienes, and Acetylenes via Hydroboration13
Hydroamination of Alkenes88
Hydrocyanation of Alkenes and Alkynes75
Hydrocyanation of Conjugated Carbonyl Compounds25
Hydroformylation Reaction56
Hydrogen-bonding-mediated Directed Osmium Dihydroxylation76
Hydrogenolysis of Benzyl Groups Attached to Oxygen, Nitrogen, or Sulfur7
Indoles via Palladium-catalyzed Cyclization76
Intermolecular C-H Insertions of Carbenoids75
Intermolecular Metal-Catalyzed Carbenoid Cyclopropanations57
Intramolecular Diels-Alder Reaction32
Intramolecular Heck Reaction60
Intramolecular Michael Reaction47
Intramolecular Reactions of Diazocarbonyl Compounds26
Ionic and Organometallic-Catalyzed Organosilane Reductions71
Iron-catalyzed Cross-coupling Reactions83
Jacobsen Reaction1
Japp-Klingemann Reaction10
Ketene Cycloadditions45
Knoevenagel Condensation15
Krapcho Dealkoxycarbonylation Reaction of Esters with alpha-Electron-withdrawing Substituents81
Kulinkovich Cyclopropanation of Carboxylic Acid Derivatives77
Lateral Lithiation Reactions Promoted by Heteroatomic Substituents47
Leuckart Reaction5
Lithioalkenes from Arenesulfonylhydrazones39
Mannich Reaction1
McMurry Coupling and Related Reactions82
Metalation Reaction with Organolithium Compounds8
Michael Reaction10
Microbial Arene Oxidations63
Mitsunobu Reaction42
Modern Methods to Prepare Monofluoroaliphatic Compounds21
Molybdenum-catalyzed Asymmetric Allylic Alkylations84
Nazarov Cyclization45
Nef Reaction38
Nitrosation of Aliphatic Carbon Atoms7
Nucleophilic Additions of Perfluoroalkyl Groups91
Olefin Ring-closing Metathesis89
Olefin Synthesis via Deoxygenation of Vicinal Diols30
Olefins from Amines: The Hofmann Elimination Reaction and Amine Oxide Pyrolysis11
Oppenauer Oxidation6
Organocopper Reagents: Substitution, Conjugate Addition, Carbo/Metallo-cupration, and Other Reactions41
Oxidation of Alcohols by Modified Oxochromium(VI)-Amine Complexes53
Oxidation of Alcohols to Carbonyl Compounds via Alkoxysulfonium Ylides: The Moffatt, Swern, and Related Oxidations39
Oxidation of Carbonyl Compounds with Organohypervalent Iodine Reagents54
Oxidation of Phenolic Compounds with Organohypervalent Iodine Reagents57
Oxidative Cleavage of Furans87
Oxidative Decarboxylation of Acids by Lead Tetraacetate19
Oxoammonium and Nitroxide-catalyzed Oxidations of Alcohols74
Palladium-Catalyzed Vinylation of Organic Halides27
Passerini Reaction65
Pauson-Khand Cycloaddition Reaction for Synthesis of Cyclopentenones40
Pechmann Reaction7
Periodic Acid Oxidation2
Perkin Reaction and Related Reactions1
Persulfate Oxidation of Phenols and Arylamines (The Elbs and the Boyland-Sims Oxidations)35
Peterson Olefination Reaction38
Phosphorus Addition at sp2 Carbon36
Photocyclization of Stilbenes and Related Molecules30
Pictet-Spengler Synthesis of Tetrahydroisoquinolines and Related Compounds6
Polonovski Reaction39
Preparation and Applications of Functionalized Organozinc Compounds58
Preparation of 3,4-Dihydroisoquinolines and Related Compounds by the Bischler-Napieralski Reaction6
Preparation of Aliphatic Fluorine Compounds2
Preparation of Amines by Reductive Alkylation4
Preparation of Aromatic Arsonic and Arsinic Acids by the Bart, Béchamp, and Rosenmund Reactions2
Preparation of Aromatic Fluorine Compounds from Diazonium Fluoborates: The Schiemann Reaction5
Preparation of Ketenes and Ketene Dimers3
Preparation of Ketones from the Reaction of Organolithium Reagents with Carboxylic Acids18
Preparation of Olefins by the Pyrolysis of Xanthates. The Chugaev Reaction12
Preparation of Thiazoles6
Preparation of Thiophenes and Tetrahydrothiophenes6
Preparation of Unsymmetrical Biaryls by the Diazo Reaction and the Nitrosoacetylamine Reaction2
Preparation of alpha beta-Unsaturated Carbonyl Compounds and Nitriles by Selenoxide Elimination44
Pschorr Synthesis and Related Diazonium Ring Closure Reactions9
Pummerer Reaction of Sulfinyl Compounds40
Radical Cyclization Reactions48
Ramberg-Bäcklund Reaction62
Ramberg-Bäcklund Rearrangement25
Reaction of Diazomethane and Its Derivatives with Aldehydes and Ketones8
Reaction of Halogens with Silver Salts of Carboxylic Acids9
Reactions of Diazoacetic Esters with Alkenes, Alkynes, Heterocyclic, and Aromatic Compounds18
Reduction and Related Reactions of alpha beta-Unsaturated Compounds with Metals in Liquid Ammonia23
Reduction by Metal Alkoxyaluminum Hydrides. Part II. Carboxylic Acids and Derivatives, Nitrogen Compounds, and Sulfur Compounds36
Reduction with Aluminum Alkoxides (The Meerwein-Ponndorf-Verley Reduction)2
Reduction with Diimide40
Reductions by Lithium Aluminum Hydride6
Reductions by Metal Alkoxyaluminum Hydrides34
Reductions with Samarium(II) Iodide46
Reductive Aminations of Carbonyl Compounds with Borohydride and Borane Reducing Agents59
Reductive Dehalogenation of Polyhalo Ketones with Low-Valent Metals and Related Reducing Agents29
Reformatsky Reaction (1)1
Reformatsky Reaction (2)22
Reimer-Tiemann Reaction28
Replacement of Alcoholic Hydroxy Groups by Halogens and Other Nucleophiles via Oxyphosphonium Intermediates29
Replacement of the Aromatic Primary Amino Group by Hydrogen2
Resolution of Alcohols2
Retro-Diels-Alder Reaction. Part II. Dienophiles with One or More Heteroatoms53
Retro–Diels–Alder Reaction. Part I. C–C Dienophiles52
Ring-Expanding Carbonylation of Epoxides86
Ritter Reaction17
Rosenmund Reduction of Acid Chlorides to Aldehydes4
Schmidt Reaction (1)3
Selenium Dioxide Oxidation (1)5
Selenium Dioxide Oxidation (2)24
Sensitized Photooxygenation of Olefins20
Simmons-Smith Cyclopropanation Reaction58
Skraup Synthesis of Quinolines7
Smiles and Related Rearrangements of Aromatic Systems18
Sommelet Reaction8
Stille Reaction50
Stobbe Condensation6
Substitution Reactions Using Organocopper Reagents22
Substitution and Addition Reactions of Thiocyanogen3
Syntheses Using Alkyne-Derived Alkenyl- and Alkynylaluminum Compounds32
Synthesis of 5-Hydroxyindoles by the Nenitzescu Reaction20
Synthesis of Acetylenes5
Synthesis of Aldehydes from Carboxylic Acids8
Synthesis of Aliphatic and Alicyclic Nitro Compounds12
Synthesis of Benzoins4
Synthesis of Benzoquinones by Oxidation4
Synthesis of Isoquinolines by the Pomeranz-Fritsch Reaction6
Synthesis of Ketones from Acid Halides and Organometallic Compounds of Magnesium, Zinc, and Cadmium8
Synthesis of Nucleosides55
Synthesis of Peptides with Mixed Anhydrides12
Synthesis of Phenols and Quinones via Fischer Carbenes70
Synthesis of Phosphonic and Phosphinic Acids6
Synthesis of Substituted Ferrocenes and Other pi-Cyclopentadienyl-Transition Metal Compounds17
Synthesis of beta-Lactams9
Synthetic Applications of Phosphoryl-Stabilized Anions25
Synthetic Uses of Tosylmethyl Isocyanide (TosMIC)57
Tandem Vicinal Difunctionalization: beta-Addition to alpha beta-Unsaturated Carbonyl Substrates Followed by alpha-Functionalization38
The Asymmetric Vinylogous Mukaiyama Aldol Reaction98
The Aza-Cope/Mannich Reaction75
The Barton-McCombie Reaction77
The Boronic Acid Mannich Reaction83
The Catalytic, Enantioselective Michael Reaction90
The Julia-Kocienski Olefination95
The Neber Rearrangement78
The Saegusa Oxidation and Related Procedures98
The Schmidt Reaction (2)78
The Tishchenko Reaction86
The Wacker Oxidation84
Thiele-Winter Acetoxylation of Quinones19
Tin(II) Enolates in the Aldol, Michael, and Related Reactions46
Transformation of Glycals into 2,3-Unsaturated Glycosyl Derivatives62
Transition Metal Catalyzed Hydroacylation96
Transition-metal-catalyzed a-Arylation of Enolates76
Twofold Extrusion Reactions78
Vilsmeier Reaction of Fully Conjugated Carbocycles and Heterocycles49
Vilsmeier Reaction. 2. Reactions with Compounds Other Than Fully Conjugated Carbocycles and Heterocycles56
Vinylcyclopropane-Cyclopentene Rearrangement33
Von Braun Cyanogen Bromide Reaction7
Willgerodt Reaction3
Wittig Reaction14
Wolff-Kishner Reduction4
Zinin Reaction of Nitroarenes20