| Title | Author | Volume | Year | | Reductive Cyclization of 2-Nitro- and β-Nitrostyrenes, 2-Nitrobiphenyls, and 1-Nitro-1,3-Dienes to Indoles, Carbazoles, and Pyrroles | Berkowitz, W.; Söderberg, B. C. G. | 111 | 2022 |
| Ring-Opening Reactions of Epoxides With Titanium(III) Reagents | RajanBabu, T. V.; Nugent, W. A.; Halder, S. | 111 | 2022 |
| Enantioselective Epoxide Opening | Nakajima, M.; Kotani, S.; Sugiura, M. | 110 | 2022 |
| Radical Allylation, Vinylation, Allenylation, Alkynylation, and Propargylation Reactions Using Tin Reagents | Rosenstein, I. | 110 | 2022 |
| Cyclization Reactions of Nitrogen-centered Radicals | McCombie, S. W.; Quiclet-Sire, B.; Zard, S. Z. | 108 | 2021 |
| Extrusion Reactions Affording Aromatic Systems, Dienes and Polyenes | Guziec Jr., J. S.; Guziec, L. | 109 | 2022 |
| Transition-Metal-Catalyzed Aminooxygenation of Alkenes | Chemler, S. R.; Chen, D.; Karyakarte, S. D.; Shikora, J. M.; Wdowik, T. | 108 | 2021 |
| Hauser-Kraus and Related Annulations | De Koning, C. B.; Georgiou, K. H.; Michael, J. P.; Rousseau, A. L. | 107 | 2021 |
| Enantioselective Hydroformylation | Tazawa, T.; Phanopoulos, A.; Nozaki, K. | 107 | 2021 |
| The Catalytic Enantioselective Stetter Reaction | Flanigan, D. M.; Ozboya, K. E.; Muñoz, A.; Rovis, T.; Tanpure, S. D.; Blakemore, P. R. | 106 | 2021 |
| Alkene Cross-Metathesis Reactions | Grela, K.; Kajetanowicz, A.; Szadkowska, A.; Czaban-Józwiak, J. | 106 | 2021 |
| The Matteson Reaction | Matteson, D. S.; Collins, B. S. L.; Aggarwal, V. K.; Ciganek, E. | 105 | 2021 |
| Reactions of Diboron Reagents with Unsaturated Compounds | Fernández, E.; Cuenca, A. B. | 105 | 2021 |
| Enantioselective Halofunctionalization of Alkenes | Ashtekar, K. D.; Jagnathan, A.; Borhan, B.; Whitehead, D. C. | 105 | 2021 |
| Transition‐Metal‐Mediated and Transition‐Metal‐Catalyzed Carbon–Fluorine Bond Formation | Neumann, C. N.; Ritter, T. | 104 | 2020 |
| The Piancatelli Reaction | Marin, L.; Schulz, E.; Lebœuf, D.; Gandon, V. | 104 | 2020 |
| Kinetic Resolution and Desymmetrization of Alcohols and Amines by Nonenzymatic, Enantioselective Acylation | Frost, A. B.; Greenhalgh, M. D.; Munday, E. S.; Musolino, S. F.; Taylor, J. E.; Smith, A.D. | 104 | 2020 |
| Propargylic Coupling Reactions via Bimetallic Alkyne Complexes | Green, J. R.; Nicholas, K. M. | 103 | 2020 |
| 3 + 2 Cycloadditions of Azomethine Imines | Grošelj, U.; Svete, J. | 103 | 2020 |
| Transition‐Metal‐Catalyzed Alkyne Hydroarylation with Arylmetals and Aryl Halides | Yamamoto, Y. | 103 | 2020 |
| Alkyne Metathesis | Lee, D.; Volchkov, I.; Yun, S. Y. | 102 | 2020 |
| The Brook Rearrangement | Gao, L.; Yang, W.; Wu, W.; Song, Z. | 102 | 2020 |
| Dihydropyrans by Cycloadditions of Oxadienes | Martel, A.; Dhal, R.; Gaulon, C.; Laurent, M. Y.; Dujardin, G. | 101 | 2020 |
| Catalytic, Enantioselective, Copper-Boryl Additions to Alkenes | Hoveyda, A. H.; Ming, J. K.; Lee, K. A.; Lee, J. | 100 | 2019 |
| Palladium-Catalyzed Amination of Aryl Halides | Hartwig, J. F.; Shaughnessy, K. H.; Shekhar, S.; Green, R. A. | 100 | 2019 |
| Catalyst-Controlled Glycosylation | Jacobsen, E. N.; Levi, S. M. | 100 | 2019 |
| Catalytic, Enantioselective Fluorination Reactions | Toste, F. D.; Thornbury, R. | 100 | 2019 |
| Catalytic, Enantioselective, C–H Functionalization to Form Carbon-Carbon Bonds | Yu, J.-Q.; Wu, Q.-F.; Chen, G.; He, J. | 100 | 2019 |
| Ortho-Directed C–H Alkylation of Substituted Benzenes | Chatani, N.; Ano, Y. | 100 | 2019 |
| The Suzuki-Miyaura Cross-Coupling Reaction | Lloyd-Jones, G. C.; Pagett, A. B. | 100 | 2019 |
| Carbon-Carbon Bond Formation by Metallaphotoredox Catalysis | MacMillan, D. W. C.; Nacsa, E. | 100 | 2019 |
| Hydrofunctionalization of Alkenes by Hydrogen Atom Transfer | Shenvi, R. A.; Matos, J. L. M.; Green, S. A. | 100 | 2019 |
| Catalytic, Enantioselective Transfer Hydrogenation | Kitamura, M.; Yoshimura, M. | 100 | 2019 |
| Enantioselective Lithiation-Substitution of Nitrogen-Containing Heterocycles | O'Brien, P.; Kasten, K.; Seling, N. | 100 | 2019 |
| The Catalytic, Enantioselective Favorskii Reaction | Carreira, E. M.; Sempere, Y. | 100 | 2019 |
| Copper Catalyzed, Enantioselective Hydrofunctionalization of Alkenes | Buchwald, S. L.; Wang, H. | 100 | 2019 |
| The Negishi Cross-Coupling Reaction | Organ, M. G.; Diner, C. | 100 | 2019 |
| Generation and Trapping of Functionalized Aryl- and Heteroarylmagnesium and -Zinc Compounds | Knochel, P.; Lutter, F. H.; Hofmayer, M. S.; Hammann, J. M.; Malakhov, V. | 100 | 2019 |
| Iridium-catalyzed, Enantioselective, Allylic Alkylations with Carbon Nucleophiles | Qu, J.-P.; Helmchen, G. | 99 | 2019 |
| Addition of Non-stabilized Carbon-based Nucleophilic Reagents to Chiral N-Sulfinyl Imines | Herbage, M. A.; Savoie, J.; Sieber, J. D.; Desrosiers, J.-N.; Zhang, Y.; Marsini, M. A.; Fandrick, K. R.; Rivalti, D.; Senanayake, C. H. | 99 | 2019 |
| The Asymmetric Vinylogous Mukaiyama Aldol Reaction | Cordes, M. H. C.; Kalesse, M. | 98 | 2019 |
| The Saegusa Oxidation and Related Procedures | Le Bras, J.; Muzart, J. | 98 | 2019 |
| Amide-forming Ligation Reactions | Pattabiraman, V. R.; Ogunkoya, A. O.; Bode, J. W. | 97 | 2019 |
| 2+2+2 Cycloadditions of Alkynes with Heterocumulenes and Nitriles | Staudaher, N. D.; Stolley, R. M.; Louie, J. | 97 | 2019 |
| Transition Metal Catalyzed Hydroacylation | Dong, V. M.; Kou, K. G. M.; Le, D. N. | 96 | 2018 |
| Catalytic, Enantioselective Hydrogenation of Heteroaromatic Compounds | Shi, L.; Zhou, Y.-G. | 96 | 2018 |
| Asymmetric Synthesis of β-Lactams by the Staudinger Reaction | Landa, A.; Mielgo, A.; Oiarbide, M.; Palomo, C. | 95 | 2018 |
| The Julia-Kocienski Olefination | Blakemore, P. R.; Sephton, S. M.; Ciganek, E. | 95 | 2018 |
| 3+2 Dipolar Cycloadditions of Cyclic Nitrones with Alkenes | Brandi, A.; Cardona, F.; Cicchi, S.; Cordero, F. M.; Goti, A. | 94 | 2017 |
| Asymmetric Rhodium-Catalyzed 1,4-Addition of Organoboron Reagents | Burns, A. R.; Lam, H. W.; Roy, I. D. | 93 | 2017 |
| Cyclizations of Vinyl and Aryl Azides into Pyrroles, Indoles, Carbazoles, and Related Fused Pyrroles | Berkowitz, W. F.; McCombie, S. W. | 92 | 2017 |
| Gold-catalyzed Cyclizations of Alkynes with Alkenes and Arenes | Echavarren, A. M.; Muratore, M. E.; López-Carrillo, V.; Escribano-Cuesta, Huguet, N.; Obradors, C. | 92 | 2017 |
| Nucleophilic Additions of Perfluoroalkyl Groups | Beier, P.; Zibinsky, M.; Surya Prakash, G. K. | 91 | 2016 |
| The Catalytic, Enantioselective Michael Reaction | Reyes, E.; Uria, U.; Vicario, J. L.; Vicario, L. | 90 | 2016 |
| Olefin Ring-closing Metathesis | Yet, L. | 89 | 2016 |
| Hydroamination of Alkenes | Reznichenko, A. L.; Hultzsch, K. C. | 88 | 2015 |
| Carbozincation Reactions of Carbon-Carbon Multiple Bonds | Sklute, G.; Cavender, H.; Marek, I. | 87 | 2015 |
| Cycloaddition and Electrocyclization Reactions of Vinylketenes, Allenylketenes, and Alkynylketenes | Fu, N.; Tidwell, T. T. | 87 | 2015 |
| Oxidative Cleavage of Furans | Merino, P. | 87 | 2015 |
| The Tishchenko Reaction | Koskinen, A. M. P.; Kataja, A. O.. | 86 | 2015 |
| Ring-Expanding Carbonylation of Epoxides | Kramer, J. W.; Rowley, J. M.; Coates, G. W. | 86 | 2015 |
| Copper-Catalyzed Amination of Aryl and Alkenyl Electrophiles | Shaughnessy, K. H.; Ciganek, E.; DeVasher, R. B. | 85 | 2014 |
| The Wacker Oxidation | Michel, B. W.; Steffens, L. D.; Sigman, M. S. | 84 | 2014 |
| Molybdenum-catalyzed Asymmetric Allylic Alkylations | Moberg, C. | 84 | 2014 |
| Iron-catalyzed Cross-coupling Reactions | Nakamura, E.; Hatakeyama, T.; Ito, S.; Ishizuka, K.; Ilies, L.; Nakamura, M. | 83 | 2014 |
| The Boronic Acid Mannich Reaction | Pyne, S. G.; Tang, M. | 83 | 2014 |
| Catalytic Asymmetric Ketene 2 + 2 and 4 + 2 Cycloadditions | Nelson, S. G.; Dura, R. D.; Peelen, T. J. | 82 | 2013 |
| McMurry Coupling and Related Reactions | Takeda, T.; Tsubouchi, A. | 82 | 2013 |
| Krapcho Dealkoxycarbonylation Reaction of Esters with alpha-Electron-withdrawing Substituents | Krapcho, A. P.; Ciganek, E. | 81 | 2013 |
| Cycloadditions of Carbonyl Ylides Derived from Diazocarbonyl Compounds | Hodgson, D. M.; Labande, A. H.; Muthusamy, S. | 80 | 2013 |
| Catalytic, Asymmetric, Intramolecular Carbon-Hydrogen Insertion | Doyle, M. P.; Liu, Y.; Ratnikov, M. | 80 | 2013 |
| Asymmetric Transformations by Deprotonation Using Chiral Lithium Amides | Simpkins, N. S.; Weller, M. D. | 79 | 2013 |
| Cross-coupling Reactions of Organotrifluoroborate Salts | Molander, G. A.; Jean-Gérard, L. | 79 | 2013 |
| Twofold Extrusion Reactions | Guziec, Lynn J.; Guziec, Jr., Frank S. | 78 | 2012 |
| The Neber Rearrangement | Berkowitz, William F. | 78 | 2012 |
| The Schmidt Reaction (2) | Wrobleski, A.; Coombs, Thomas C.; Huh, Chan W.; Li, Sze-Wan; Aubé, Jeffrey | 78 | 2012 |
| Kulinkovich Cyclopropanation of Carboxylic Acid Derivatives | Cha, Jun Kun; Kulinkovich, Oleg G. | 77 | 2012 |
| The Barton-McCombie Reaction | McCombie, Stuart W.; Motherwell, William B.; Tozer, Matthew | 77 | 2012 |
| Indoles via Palladium-catalyzed Cyclization | Cacchi, Sandro; Fabrizi, Giancarlo; Googiamani, Antonella | 76 | 2012 |
| Transition-metal-catalyzed a-Arylation of Enolates | Prim, Damien; Marque, Sylvia; Gaucher, Anne; Campagne, Jean-Marc | 76 | 2012 |
| Hydrogen-bonding-mediated Directed Osmium Dihydroxylation | Donohoe, Timothy J.; Bataille, Carole J. R.; Innocenti, Paolo | 76 | 2012 |
| The Aza-Cope/Mannich Reaction | Overman, Larry E.; Humphreys, Philip G.; Welmaker, Gregory S. | 75 | 2011 |
| Cross-Coupling with Organosilicon Compounds | Chang, Wen-Tau T.; Smith, Russell C.; Regens, C. S.; Bailey, Aaron D.; Werner, Nathan S.; Denmark, Scott E. | 75 | 2011 |
| Intermolecular C-H Insertions of Carbenoids | Davies, Huw M. L.; Pelphrey, Phillip M. | 75 | 2011 |
| Hydrocyanation of Alkenes and Alkynes | Rajanbabu, Thaliyil V. | 75 | 2011 |
| Asymmetric Epoxidation Of Electron-Deficient Alkenes | Porter, Michael J.; Skidmore, John | 74 | 2009 |
| Oxoammonium and Nitroxide-catalyzed Oxidations of Alcohols | Bobbitt, James M.; Brückner, Christian; Merbouh, Nabyl | 74 | 2009 |
| Catalytic Asymmetric Hydrogenation Of C=N Functions | Blaser, Hans-Ulrich; Spindler, Felix | 74 | 2009 |
| Allylboration of Carbonyl Compounds | Lachance, Hugo; Hall, Dennis G. | 73 | 2008 |
| Desulfonylation Reactions | Alonso, Diego A.; Nájera, Carmen | 72 | 2008 |
| Electrophilic Amination of Carbanions, Enolates, and Their Surrogates | Ciganek, Engelbert | 72 | 2008 |
| Ionic and Organometallic-Catalyzed Organosilane Reductions | Larson, Gerald L.; Fry, James L. | 71 | 2008 |
| Synthesis of Phenols and Quinones via Fischer Carbenes | Waters, Marcey L.; Wulff, William D. | 70 | 2008 |
| Catalytic Asymmetric Strecker Reaction | Shibasaki, Masakatsu; Kanai, Motomu; Mita, Tsuyoshi | 70 | 2008 |
| Electrophilic Fluorination with N-F Reagents | Baudoux, Jérôme; Cahard, Dominique | 69 | 2007 |
| Dioxirane Oxidations of Compounds Other Than Alkenes | Adam, Waldemar; Zhao, Cong-Gui; Jakka, Kavitha | 69 | 2007 |
| Glycosylation on Polymer Supports | Bufali, Simone; Seeberger, Peter H. | 68 | 2007 |
| Cotrimerizations of Acetylenic Comounds | Agenet, N.; Buisine, O.; Slowinski, F.; Gandon, V.; Aubert, C; Malacria, M. | 68 | 2007 |
| Benzylic Activation and Stereocontrol in Tricarbonyl(arene)chromium Complexes | Uemura, Motokazu | 67 | 2006 |
| Catalytic Enantioselective Aldol Addition Reactions | Carreira, Erick M.; Fettes, Alec; Marti, Christiane | 67 | 2006 |
| Asymmetric Dihydroxylation of Alkenes | Noe, Mark C.; Letavic, Michael A.; Snow, Sheri L.; McCombie, Stuart | 66 | 2005 |
| Allylic Trihaloacetimidate Rearrangment | Overman, Larry E.; Carpenter, Nancy E. | 66 | 2005 |
| Diels-Alder Reactions of Imino Dienophiles | Heintzelman, Geoffrey R.; Meigh, Ivona R.; Mahajan, Yogesh R.; Weinreb, Steven M. | 65 | 2005 |
| Passerini Reaction | Banfi, Luca; Riva, Renata | 65 | 2005 |
| Addition of Organochromium Reagents to Carbonyl Compounds | Takai, Kazuhiko | 64 | 2004 |
| Glycosylation with Sulfoxides and Sulfinates as Donors or Promoters | Crich, David; Lim, Linda B. L. | 64 | 2004 |
| Additions of Allyl, Allenyl, and Propargylstannanes to Aldehydes and Imines | Gung, Benjamin W. | 64 | 2004 |
| Cu, Ni, and Pd Mediated Homocoupling Reactions in Biaryl Syntheses: The Ullmann Reaction | Nelson, Todd D.; Crouch, David, R. | 63 | 2004 |
| Microbial Arene Oxidations | Johnson, Roy A. | 63 | 2004 |
| Biginelli Dihydropyrimidine Synthesis | Kappe, C. Oliver; Stadler, Alexander | 63 | 2004 |
| Transformation of Glycals into 2,3-Unsaturated Glycosyl Derivatives | Ferrier, Robert J.; Zubkov, Oleg A. | 62 | 2003 |
| Alpha-Hydroxy Ketone (alpha-Ketol) and Related Rearrangements | Paquette, Leo A.; Hofferberth, John E. | 62 | 2003 |
| Ramberg-Bäcklund Reaction | Taylor, Richard J. K.; Casy, Guy | 62 | 2003 |
| Alpha-Hydroxylation of Enolates and Silyl Enol Ethers | Bang-Chen, Chi; Zhou, Ping; Davis, Franklin A.; Ciganek, Engelbert | 62 | 2003 |
| Dioxirane Epoxidation of Alkenes | Adam, Waldemar; Saha-Möller, Chantu R.; Zhao, Cong-Gui | 61 | 2002 |
| 3+2 Cycloaddition of Trimethylenemethane and its Synthetic Equivalents | Yamago, S.; Nakamura, E. | 61 | 2003 |
| Intramolecular Heck Reaction | Link, J. T. | 60 | 2002 |
| Epoxide Migration (Payne Rearrangement) and Related Reactions | Hanson, Robert M. | 60 | 2002 |
| Reductive Aminations of Carbonyl Compounds with Borohydride and Borane Reducing Agents | Baxter, Ellen W.; Reitz, Allen B. | 59 | 2001 |
| Preparation and Applications of Functionalized Organozinc Compounds | Knochel, Paul; Millot, Nicolas; Rodriguez, Alain L.; Tucker, Charles E. | 58 | 2001 |
| Simmons-Smith Cyclopropanation Reaction | Charette, André B.; Beauchemin, André | 58 | 2001 |
| Synthetic Uses of Tosylmethyl Isocyanide (TosMIC) | Van Leusen, Daan; van Leusen, Albert M. | 57 | 2001 |
| Oxidation of Phenolic Compounds with Organohypervalent Iodine Reagents | Moriarty, Robert M.; Prakash, Om | 57 | 2001 |
| Intermolecular Metal-Catalyzed Carbenoid Cyclopropanations | Davies, Huw M. L.; Antoulinakis, Evan G. | 57 | 2001 |
| Vilsmeier Reaction. 2. Reactions with Compounds Other Than Fully Conjugated Carbocycles and Heterocycles | Jones, Gurnos; Stanforth, Stephen P. | 56 | 2000 |
| Hydroformylation Reaction | Ojima, Iwao; Tsai, Chung-Ying; Tzamarioudaki, Maria; Bonafoux, Dominique | 56 | 2000 |
| Synthesis of Nucleosides | Vorbrüggen, Helmut; Ruh-Pohlenz, Carmen | 55 | 1999 |
| Oxidation of Carbonyl Compounds with Organohypervalent Iodine Reagents | Moriarty, Robert M.; Prakash, Om | 54 | 1999 |
| Aromatic Substitution by the SRN1 Reaction | Rossi, Roberto A.; Pierini, Andrea B.; Santiago, Ana N. | 54 | 1999 |
| Retro-Diels-Alder Reaction. Part II. Dienophiles with One or More Heteroatoms | Rickborn, Bruce | 53 | 1998 |
| Oxidation of Alcohols by Modified Oxochromium(VI)-Amine Complexes | Luzzio, Frederick A. | 53 | 1998 |
| Enantioselective Reduction of Ketones | Itsuno, Shinichi | 52 | 1998 |
| Retro–Diels–Alder Reaction. Part I. C–C Dienophiles | Rickborn, Bruce | 52 | 1998 |
| 4+3 Cycloaddition Reactions | Rigby, J. H.; Pigge, F. C. | 51 | 1997 |
| Catalyzed a-Hydroxyalkylation and a-Aminoalkylation of Activated Olefins (The Morita–Baylis–Hillman Reaction) | Ciganek, Engelbert | 51 | 1997 |
| Asymmetric Aldol Reactions Using Boron Enolates | Cowden, Cameron J.; Paterson, Ian | 51 | 1997 |
| Stille Reaction | Farina, Vittorio; Krishnamurthy, Venkat; Scott, William J. | 50 | 1997 |
| Carbon-Carbon Bond-Forming Reactions Promoted by Trivalent Manganese | Melikyan, Gagik G. | 49 | 1997 |
| 6+4 Cycloaddition Reactions | Rigby, J. H. | 49 | 1997 |
| Vilsmeier Reaction of Fully Conjugated Carbocycles and Heterocycles | Jones, Gurnos; Stanforth, Stephen P. | 49 | 1997 |
| Radical Cyclization Reactions | Giese, B.; Kopping, B.; T. Göbel, Dickhaut, J.; Thoma, G.; Kulicke, K. J.; Trach, F. | 48 | 1995 |
| Asymmetric Epoxidation of Allylic Alcohols: The Katsuki-Sharpless Epoxidation Reaction | Katsuki, Tsutomu; Martin, Victor S. | 48 | 1995 |
| Intramolecular Michael Reaction | Little, R.; Daniel; Masjedizadeh, Mohammad R.; Wallquist, Olof (in part); McLoughlin, Jim I. (in part) | 47 | 1995 |
| Lateral Lithiation Reactions Promoted by Heteroatomic Substituents | Clark, Robin D.; Jahangir, Alam | 47 | 1995 |
| Reductions with Samarium(II) Iodide | Molander, Gary A. | 46 | 1994 |
| 2,3-Wittig Rearrangement | Nakai, Takeshi; Mikami, Koichi | 46 | 1994 |
| Tin(II) Enolates in the Aldol, Michael, and Related Reactions | Mukaiyama, Teruaki; Kobayashi, Shu | 46 | 1994 |
| Ketene Cycloadditions | Hyatt, John; Raynolds, Peter W. | 45 | 1994 |
| Nazarov Cyclization | Habermas, Karl L.; Denmark, Scott E.; Jones, Todd K. | 45 | 1994 |
| Enone Olefin 2+2 Photochemical Cycloadditions | Crimmins, Michael T.; Reinhold, Tracy L. | 44 | 1993 |
| Preparation of alpha beta-Unsaturated Carbonyl Compounds and Nitriles by Selenoxide Elimination | Reich, Hans J.; Wollowitz, Susan | 44 | 1993 |
| Baeyer-Villiger Oxidation of Ketones and Aldehydes | Krow, Grant R. | 43 | 1993 |
| Anion-Assisted Sigmatropic Rearrangements | Wilson, Stephen R. | 43 | 1993 |
| Carbonyl Methylenation and Alkylidenation Using Titanium-Based Reagents | Pine, Stanley H. | 43 | 1993 |
| Mitsunobu Reaction | Hughes, David L. | 42 | 1992 |
| Birch Reduction of Aromatic Compounds | Rabideau, Peter W.; Marcinow, Zbigniew | 42 | 1992 |
| Organocopper Reagents: Substitution, Conjugate Addition, Carbo/Metallo-cupration, and Other Reactions | Lipshutz, Bruce H.; Sengupta, Saumitra | 41 | 1992 |
| Divinylcyclopropane-Cycloheptadiene Rearrangement | Hudlicky´, Tomásˇ; Fan, Rulin; Reed, Josephine W.; Gadamasetti, Kumar G. | 41 | 1992 |
| Catalyzed Nucleophilic Addition of Aldehydes to Electrophilic Double Bonds | Stetter, Hermann; Kuhlmann, Heinrich | 40 | 1991 |
| Pummerer Reaction of Sulfinyl Compounds | DeLucchi, Ottorino; Miotti, Umberto; Modena, Giorgio | 40 | 1991 |
| Reduction with Diimide | Pasto, Daniel J.; Taylor, Richard T. | 40 | 1991 |
| Pauson-Khand Cycloaddition Reaction for Synthesis of Cyclopentenones | Schore, Neil E. | 40 | 1991 |
| Oxidation of Alcohols to Carbonyl Compounds via Alkoxysulfonium Ylides: The Moffatt, Swern, and Related Oxidations | Tidwell, Thomas T. | 39 | 1990 |
| Polonovski Reaction | Grierson, David | 39 | 1990 |
| Lithioalkenes from Arenesulfonylhydrazones | Chamberlin, A.; Richard; Bloom, Steven H. | 39 | 1990 |
| Nef Reaction | Pinnick, Harold W. | 38 | 1990 |
| Tandem Vicinal Difunctionalization: beta-Addition to alpha beta-Unsaturated Carbonyl Substrates Followed by alpha-Functionalization | Chapdelaine, Marc J.; Hulce, Martin | 38 | 1990 |
| Peterson Olefination Reaction | Ager, David J. | 38 | 1990 |
| Electrophilic Substitution of Allylsilanes and Vinylsilanes | Fleming, Ian; Dunoguès, Jacques; Smithers, Roger | 37 | 1989 |
| Chiral Synthons by Ester Hydrolysis Catalyzed by Pig Liver Esterase | Ohno, Masaji; Otsuka, Masami | 37 | 1989 |
| Reduction by Metal Alkoxyaluminum Hydrides. Part II. Carboxylic Acids and Derivatives, Nitrogen Compounds, and Sulfur Compounds | Málek, Jaroslav | 36 | 1988 |
| Phosphorus Addition at sp2 Carbon | Engel, Robert | 36 | 1988 |
| 3+2 Nitrone-Olefin Cycloaddition Reaction | Confalone, P. N.; Huie, E. M. | 36 | 1988 |
| Fluorination with Diethylaminosulfur Trifluoride and Related Aminofluorosulfuranes | Hudlicky´, Milosˇ | 35 | 1988 |
| Persulfate Oxidation of Phenols and Arylamines (The Elbs and the Boyland-Sims Oxidations) | Behrman, E. J. | 35 | 1988 |
| Beckmann Reactions: Rearrangements, Elimination-Additions, Fragmentations, and Rearrangement-Cyclizations | Gawley, Robert E. | 35 | 1988 |
| Fluorination by Sulfur Tetrafluoride | Wang, Chia-Lin J. | 34 | 1985 |
| Reductions by Metal Alkoxyaluminum Hydrides | Málek, Jaroslav | 34 | 1985 |
| Vinylcyclopropane-Cyclopentene Rearrangement | Hudlicky´, Tomásˇ; Kutchan, Toni M.; Naqvi, Saiyid M. | 33 | 1985 |
| Formation of Carbon-Carbon and Carbon-Heteroatom Bonds via Organoboranes and Organoborates | Negishi, Ei-Ichi; Idacavage, Michael J. | 33 | 1985 |
| Syntheses Using Alkyne-Derived Alkenyl- and Alkynylaluminum Compounds | Zweifel, George; Miller, Joseph A. | 32 | 1984 |
| Intramolecular Diels-Alder Reaction | Ciganek, Engelbert | 32 | 1984 |
| Addition and Substitution Reactions of Nitrile-Stabilized Carbanions | Arseniyadis, Siméon; Kyler, Keith S.; Watt, David S. | 31 | 1984 |
| Olefin Synthesis via Deoxygenation of Vicinal Diols | Block, Eric | 30 | 1984 |
| Photocyclization of Stilbenes and Related Molecules | Mallory, Frank B.; Mallory, Clelia W. | 30 | 1984 |
| Base-Promoted Isomerizations of Epoxides | Crandall, Jack K.; Apparu, Marcel | 29 | 1983 |
| Reductive Dehalogenation of Polyhalo Ketones with Low-Valent Metals and Related Reducing Agents | Noyori, Ryoji; Hayakawa, Yoshihiro | 29 | 1983 |
| Replacement of Alcoholic Hydroxy Groups by Halogens and Other Nucleophiles via Oxyphosphonium Intermediates | Castro, Bertrand R. | 29 | 1983 |
| Directed Aldol Reaction | Mukaiyama, Teruaki | 28 | 1982 |
| Friedländer Synthesis of Quinolines | Cheng, Chia-Chung; Yan, Shou-Jen | 28 | 1982 |
| Reimer-Tiemann Reaction | Wynberg, Hans; Meijer, Egbert W. | 28 | 1982 |
| Palladium-Catalyzed Vinylation of Organic Halides | Heck, Richard F. | 27 | 1982 |
| Allylic and Benzylic Carbanions Substituted by Heteroatoms | Biellmann, Jean-François; Ducep, Jean-Bernard | 27 | 1982 |
| Intramolecular Reactions of Diazocarbonyl Compounds | Burke, Steven D.; Grieco, Paul A. | 26 | 1979 |
| Heteroatom-Facilitated Lithiations | Gschwend, Heinz W.; Rodriguez, Herman R. | 26 | 1979 |
| Hydrocyanation of Conjugated Carbonyl Compounds | Nagata, Wataru; Yoshioka, Mitsuru | 25 | 1977 |
| Synthetic Applications of Phosphoryl-Stabilized Anions | Wadsworth, William S., Jr. | 25 | 1977 |
| Ramberg-Bäcklund Rearrangement | Paquette, Leo A. | 25 | 1977 |
| Selenium Dioxide Oxidation (2) | Rabjohn, Norman | 24 | 1976 |
| Arylation of Unsaturated Compounds by Diazonium Salts (The Meerwein Arylation Reaction) | Rondestvedt, Jr., Christian S. | 24 | 1976 |
| Ester Cleavages via SN2-Type Dealkylation | McMurry, John E. | 24 | 1976 |
| Homogeneous Hydrogenation Catalysts in Organic Solvents | Birch, Arthur J.; Williamson, David H. | 24 | 1976 |
| Alkenes from Tosylhydrazones | Shapiro, Robert H. | 23 | 1976 |
| Acyloin Condensation | Bloomfield, Jordan J.; Owsley, Dennis C.; Nelke, Janice M. | 23 | 1976 |
| Reduction and Related Reactions of alpha beta-Unsaturated Compounds with Metals in Liquid Ammonia | Caine, Drury | 23 | 1976 |
| Reformatsky Reaction (2) | Rathke, Michael W. | 22 | 1975 |
| Clemmensen Reduction of Ketones in Anhydrous Organic Solvents | Vedejs, E. | 22 | 1975 |
| Substitution Reactions Using Organocopper Reagents | Posner, Gary H. | 22 | 1975 |
| Claisen and Cope Rearrangements | Rhoads, Sara Jane; Raulins, N. Rebecca | 22 | 1975 |
| Modern Methods to Prepare Monofluoroaliphatic Compounds | Sharts, Clay M.; Sheppard, William A. | 21 | 1974 |
| Fluorination with Sulfur Tetrafluoride | Boswell, Jr., G. A.; Ripka, W. C.; Scribner, R. M.; Tullock, C. W. | 21 | 1974 |
| Zinin Reaction of Nitroarenes | Porter, H. K. | 20 | 1973 |
| Synthesis of 5-Hydroxyindoles by the Nenitzescu Reaction | Allen, George R., Jr. | 20 | 1973 |
| Sensitized Photooxygenation of Olefins | Denny, R. W.; Nickon, A. | 20 | 1973 |
| Cyclopropanes from Unsaturated Compounds, Methylene Iodide, and Zinc-Copper Couple | Simmons, H. E.; Cairns, T. L.; Vladuchick, Susan A.; Hoiness, Connie M. | 20 | 1973 |
| Oxidative Decarboxylation of Acids by Lead Tetraacetate | Sheldon, Roger A.; Kochi, Jay K. | 19 | 1972 |
| Thiele-Winter Acetoxylation of Quinones | McOmie, J. F. W.; Blatchly, J. M. | 19 | 1972 |
| Formation of Carbon-Carbon Bonds via π-Allylnickel Compounds | Semmelhack, Martin F. | 19 | 1972 |
| Conjugate Addition Reactions of Organocopper Reagents | Posner, Gary H. | 19 | 1972 |
| Base-Promoted Rearrangements of Quaternary Ammonium Salts | Pine, Stanley H. | 18 | 1970 |
| Reactions of Diazoacetic Esters with Alkenes, Alkynes, Heterocyclic, and Aromatic Compounds | Dave, Vinod; Warnhoff, E. W. | 18 | 1970 |
| Smiles and Related Rearrangements of Aromatic Systems | Truce, W. E.; Kreider, Eunice M.; Brand, William W. | 18 | 1970 |
| Preparation of Ketones from the Reaction of Organolithium Reagents with Carboxylic Acids | Jorgenson, Margaret J. | 18 | 1970 |
| Ritter Reaction | Krimen, L. I.; Cota, Donald J. | 17 | 1969 |
| Gamma-Alkylation and gamma-Arylation of Dianions of beta-Dicarbonyl Compounds | Harris, Thomas M.; Harris, Constance M. | 17 | 1969 |
| Synthesis of Substituted Ferrocenes and Other pi-Cyclopentadienyl-Transition Metal Compounds | Bublitz, Donald E.; Rinehart, Jr., Kenneth L. | 17 | 1969 |
| Aldol Condensation | Nielsen, Arnold T.; Houlihan, William J. | 16 | 1968 |
| Knoevenagel Condensation | Jones, G. | 15 | 1967 |
| Dieckmann Condensation | Schaefer, John P.; Bloomfield, Jordan J. | 15 | 1967 |
| Wittig Reaction | Maercker, Adalbert | 14 | 1965 |
| A-Amidoalkylations at Carbon | Zaugg, Harold E.; Martin, William B. | 14 | 1965 |
| Chapman Rearrangement | Schulenberg, J. W.; Archer, S. | 14 | 1965 |
| Formation of Carbon-Heteroatom Bonds by Free Radical Chain Additions to Carbon-Carbon Multiple Bonds | Stacey, F. W.; Harris, Jr., J. F. | 13 | 1963 |
| Free Radical Addition to Olefins to Form Carbon-Carbon Bonds | Walling, Cheves; Huyser, Earl S. | 13 | 1963 |
| Halocyclopropanes from Halocarbenes | Parham, William E.; Schweizer, Edward E. | 13 | 1963 |
| Hydration of Olefins, Dienes, and Acetylenes via Hydroboration | Zweifel, George; Brown, Herbert C. | 13 | 1963 |
| Desulfurization with Raney Nickel | Pettit, George R.; van Tamelen, Eugene E. | 12 | 1962 |
| Synthesis of Peptides with Mixed Anhydrides | Albertson, Noel F. | 12 | 1962 |
| Synthesis of Aliphatic and Alicyclic Nitro Compounds | Kornblum, Nathan | 12 | 1962 |
| Preparation of Olefins by the Pyrolysis of Xanthates. The Chugaev Reaction | Nace, Harold R. | 12 | 1962 |
| Cyclobutane Derivatives from Thermal Cycloaddition Reactions | Roberts, John D.; Sharts, Clay M. | 12 | 1962 |
| Olefins from Amines: The Hofmann Elimination Reaction and Amine Oxide Pyrolysis | Cope, Arthur C.; Trumbull, Elmer R. | 11 | 1960 |
| Favorskii Rearrangement of Haloketones | Kende, Andrew S. | 11 | 1960 |
| Arylation of Unsaturated Compounds by Diazonium Salts | Rondestvedt, Jr., Christian S. | 11 | 1960 |
| Demjanov and Tiffeneau-Demjanov Ring Expansions | Smith, Peter A. S.; Baer, Donald R. | 11 | 1960 |
| Beckmann Rearrangement | Donaruma, L.; Guy; Heldt, Walter Z. | 11 | 1960 |
| Michael Reaction | Bergmann, Ernst D.; Ginsburg, David; Pappo, Raphael | 10 | 1959 |
| Japp-Klingemann Reaction | Phillips, Robert R. | 10 | 1959 |
| Coupling of Diazonium Salts with Aliphatic Carbon Atoms | Parmerter, Stanley J. | 10 | 1959 |
| Pschorr Synthesis and Related Diazonium Ring Closure Reactions | DeTar, DeLos F. | 9 | 1957 |
| Synthesis of beta-Lactams | Sheehan, John C.; Corey, Elias J. | 9 | 1957 |
| Reaction of Halogens with Silver Salts of Carboxylic Acids | Wilson, C. V. | 9 | 1957 |
| Alkylation of Esters and Nitriles | Cope, Arthur C.; Holmes, H. L.; House, Herbert O. | 9 | 1957 |
| Baeyer-Villiger Oxidation of Aldehydes and Ketones | Hassall, C. H. | 9 | 1957 |
| Gattermann Synthesis of Aldehydes | Truce, William E. | 9 | 1957 |
| Cleavage of Non-enolizable Ketones with Sodium Amide | Hamlin, K. E.; Weston, Arthur W. | 9 | 1957 |
| Reaction of Diazomethane and Its Derivatives with Aldehydes and Ketones | Gutsche, C. David | 8 | 1954 |
| Beta Lactones | Zaugg, Harold E. | 8 | 1954 |
| Metalation Reaction with Organolithium Compounds | Gilman, Henry; Morton, Jr., John W. | 8 | 1954 |
| Synthesis of Aldehydes from Carboxylic Acids | Mosettig, Erich | 8 | 1954 |
| Sommelet Reaction | Angyal, S. J. | 8 | 1954 |
| Acylation of Ketones to Form beta-Diketones or beta-Keto Aldehydes | Hauser, Charles R.; Swamer, Frederic W.; Adams, Joe T. | 8 | 1954 |
| Synthesis of Ketones from Acid Halides and Organometallic Compounds of Magnesium, Zinc, and Cadmium | Shirley, David A. | 8 | 1954 |
| Catalytic Hydrogenation of Esters to Alcohols | Adkins, Homer | 8 | 1954 |
| Epoxidation and Hydroxylation of Ethylenic Compounds with Organic Peracids | Swern, Daniel | 7 | 1953 |
| Nitrosation of Aliphatic Carbon Atoms | Touster, Oscar | 7 | 1953 |
| Hydrogenolysis of Benzyl Groups Attached to Oxygen, Nitrogen, or Sulfur | Hartung, Walter H.; Simonoff, Robert | 7 | 1953 |
| Von Braun Cyanogen Bromide Reaction | Hageman, Howard A. | 7 | 1953 |
| Carbon-Carbon Alkylations with Amines and Ammonium Salts | Brewster, James H.; Eliel, Ernest L. | 7 | 1953 |
| Skraup Synthesis of Quinolines | Manske, R. H. F.; Kulka, Marshall | 7 | 1953 |
| Pechmann Reaction | Sethna, Suresh; Phadke, Ragini | 7 | 1953 |
| Reductions by Lithium Aluminum Hydride | Brown, Weldon G. | 6 | 1951 |
| Preparation of Thiophenes and Tetrahydrothiophenes | Wolf, Donald E.; Folkers, Karl | 6 | 1951 |
| Preparation of Thiazoles | Wiley, Richard H.; D. C. England; Behr, Lyell C. | 6 | 1951 |
| Halogen-Metal Interconversion Reaction with Organolithium Compounds | Jones, Reuben G.; Gilman, Henry | 6 | 1951 |
| Synthesis of Phosphonic and Phosphinic Acids | Kosolapoff, Gennady M. | 6 | 1951 |
| Oppenauer Oxidation | Djerassi, Carl | 6 | 1951 |
| Synthesis of Isoquinolines by the Pomeranz-Fritsch Reaction | Gensler, Walter J. | 6 | 1951 |
| Pictet-Spengler Synthesis of Tetrahydroisoquinolines and Related Compounds | Whaley, Wilson M.; Govindachari, Tutucorin R. | 6 | 1951 |
| Preparation of 3,4-Dihydroisoquinolines and Related Compounds by the Bischler-Napieralski Reaction | Whaley, Wilson M.; Govindachari, Tutucorin R. | 6 | 1951 |
| Stobbe Condensation | Johnson, William S.; Daub, Guido H. | 6 | 1951 |
| Darzens Glycidic Ester Condensation | Newman, Melvin S.; Magerlein, Barney J. | 5 | 1949 |
| Hoesch Synthesis | Spoerri, Paul E.; DuBois, Adrien S. | 5 | 1949 |
| Selenium Dioxide Oxidation (1) | Rabjohn, Norman | 5 | 1949 |
| Leuckart Reaction | Moore, Maurice L. | 5 | 1949 |
| Gattermann-Koch Reaction | Crounse, Nathan N. | 5 | 1949 |
| Friedel and Crafts Reaction with Aliphatic Dibasic Acid Anhydrides | Berliner, Ernst | 5 | 1949 |
| Preparation of Aromatic Fluorine Compounds from Diazonium Fluoborates: The Schiemann Reaction | Roe, Arthur | 5 | 1949 |
| Diels-Alder Reaction: Quinones and Other Cyclenones | Butz, Lewis L.; Rytina, Anton W. | 5 | 1949 |
| Cyanoethylation | Bruson, Herman L. | 5 | 1949 |
| Synthesis of Acetylenes | Jacobs, Thomas L. | 5 | 1949 |
| Wolff-Kishner Reduction | Todd, David | 4 | 1948 |
| Rosenmund Reduction of Acid Chlorides to Aldehydes | Mosettig, Erich; Mozingo, Ralph | 4 | 1948 |
| Synthesis of Benzoquinones by Oxidation | Cason, James | 4 | 1948 |
| Synthesis of Benzoins | Ide, Walter S.; Buck, Johannes S. | 4 | 1948 |
| Acyloins | McElvain, S. M. | 4 | 1948 |
| Preparation of Amines by Reductive Alkylation | Emerson, William S. | 4 | 1948 |
| Diels-Alder Reaction: Ethylenic and Acetylenic Dienophiles | Holmes, H. L. | 4 | 1948 |
| Diels-Alder Reaction with Maleic Anhydride | Kloetzel, Milton C. | 4 | 1948 |
| Curtius Reaction | Smith, Peter A. S. | 3 | 1946 |
| Schmidt Reaction (1) | Wolff, Hans | 3 | 1946 |
| Hofmann Reaction | Wallis, Everett L.; Lane, John F. | 3 | 1946 |
| Substitution and Addition Reactions of Thiocyanogen | Wood, John L. | 3 | 1946 |
| Azlactones | Carter, H. E. | 3 | 1946 |
| Direct Sulfonation of Aromatic Hydrocarbons and Their Halogen Derivatives | Suter, C. M.; Weston, Arthur W. | 3 | 1946 |
| Preparation of Ketenes and Ketene Dimers | Hanford, W. E.; Sauer, John C. | 3 | 1946 |
| Willgerodt Reaction | Carmack, Marvin; Spielman, M. A. | 3 | 1946 |
| Alkylation of Aromatic Compounds by the Friedel-Crafts Method | Price, Charles C. | 3 | 1946 |
| Preparation of Aromatic Arsonic and Arsinic Acids by the Bart, Béchamp, and Rosenmund Reactions | Hamilton, Cliff S.; Morgan, Jack F. | 2 | 1944 |
| Resolution of Alcohols | Ingersoll, A. W. | 2 | 1944 |
| Periodic Acid Oxidation | Jackson, Ernest L. | 2 | 1944 |
| Replacement of the Aromatic Primary Amino Group by Hydrogen | Kornblum, Nathan | 2 | 1944 |
| Preparation of Unsymmetrical Biaryls by the Diazo Reaction and the Nitrosoacetylamine Reaction | Bachmann, Werner E.; Hoffman, Roger A. | 2 | 1944 |
| Reduction with Aluminum Alkoxides (The Meerwein-Ponndorf-Verley Reduction) | Wilds, A. L. | 2 | 1944 |
| Formation of Cyclic Ketones by Intramolecular Acylation | Johnson, William S. | 2 | 1944 |
| Cannizzaro Reaction | Geissman, T. A. | 2 | 1944 |
| Preparation of Aliphatic Fluorine Compounds | Henne, Albert L. | 2 | 1944 |
| Claisen Rearrangement | Tarbell, D. Stanley | 2 | 1944 |
| Jacobsen Reaction | Irvin, Lee Smith | 1 | 1942 |
| Fries Reaction | Blatt, A. H. | 1 | 1942 |
| Mannich Reaction | Blicke, F. F. | 1 | 1942 |
| Acetoacetic Ester Condensation and Certain Related Reactions | Hauser, Charles R.; Hudson, Jr., Boyd E. | 1 | 1942 |
| Perkin Reaction and Related Reactions | Johnson, John R. | 1 | 1942 |
| Clemmensen Reduction | Martin, Elmore L. | 1 | 1942 |
| Elbs Reaction | Fieser, Louis F. | 1 | 1942 |
| Bucherer Reaction | Drake, Nathan L. | 1 | 1942 |
| Amination of Heterocyclic Bases by Alkali Amides | Leffler, Marlin T. | 1 | 1942 |
| Chloromethylation of Aromatic Compounds | Fuson, Reynold C.; McKeever, C. H. | 1 | 1942 |
| Arndt-Eistert Reaction | Bachmann, W. E.; Struve, W. S. | 1 | 1942 |
| Reformatsky Reaction (1) | Shriner, Ralph L. | 1 | 1942 |
